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GCSE CHEMISTRY

How to balance chemical equations

Step-by-step method for balancing equations, with worked examples.

Why we balance

Atoms are never created or destroyed in a reaction (conservation of mass), so there must be the same number of each type of atom on both sides of the equation.

The method

1. Write the correct formulas. 2. Count the atoms of each element on each side. 3. Add big numbers (coefficients) in front of formulas, never change the small numbers. 4. Recount until every element balances.

Top tip

Balance elements that appear in only one substance on each side first, and leave hydrogen and oxygen until last.

✏️ Worked example

Balance: CH₄ + O₂ → CO₂ + H₂O

Carbon: 1 and 1, fine. Hydrogen: 4 on the left, so put 2 in front of H₂O. Oxygen: now 2 + 2 = 4 on the right, so put 2 in front of O₂. CH₄ + 2O₂ → CO₂ + 2H₂O.

🧠 Test yourself

Balance: H₂ + O₂ → H₂O

2H₂ + O₂ → 2H₂O

Balance: Mg + HCl → MgCl₂ + H₂

Mg + 2HCl → MgCl₂ + H₂

Why can't you change H₂O to H₂O₂ to balance it?

That would make a different substance (hydrogen peroxide).

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